Head to Head
| Germany Bundesliga I | 2025/01/19 14:30 | Union Berlin v Mainz | W | 2-1 |
| Germany Bundesliga I | 2024/08/24 13:30 | Mainz v Union Berlin | D | 1-1 |
| Germany Bundesliga I | 2024/02/07 17:30 | Mainz v Union Berlin | D | 1-1 |
| Germany Bundesliga I | 2023/08/20 13:30 | Union Berlin v Mainz | W | 4-1 |
| Germany Bundesliga I | 2023/02/04 14:30 | Union Berlin v Mainz | W | 2-1 |
| Germany Bundesliga I | 2022/08/14 13:30 | Mainz v Union Berlin | D | 0-0 |
| Germany Bundesliga I | 2022/02/26 14:30 | Union Berlin v Mainz | W | 3-1 |
| Germany Bundesliga I | 2021/10/03 13:30 | Mainz v Union Berlin | W | 1-2 |
Home History
| Germany Bundesliga I | 2025/09/28 17:30 | Union Berlin v Hamburg | D | 0-0 |
| Germany Bundesliga I | 2025/09/21 13:30 | Eintracht Frankfurt v Union Berlin | W | 3-4 |
| Germany Bundesliga I | 2025/09/13 13:30 | Union Berlin v TSG Hoffenheim | L | 2-4 |
| Germany Bundesliga I | 2025/08/31 15:30 | Borussia Dortmund v Union Berlin | L | 3-0 |
| Germany Bundesliga I | 2025/08/23 13:30 | Union Berlin v VfB Stuttgart | W | 2-1 |
| Germany DFB Pokal | 2025/08/15 16:00 | Gutersloh 2000 v Union Berlin | W | 0-5 |
| Europe Friendlies | 2025/08/09 13:30 | Union Berlin v Olympiacos | L | 0-1 |
| Elite Club Friendlies | 2025/08/02 13:30 | Union Berlin v Espanyol | L | 0-1 |
Away History
| Germany Bundesliga I | 2025/09/27 13:30 | Mainz v Borussia Dortmund | L | 0-2 |
| Germany Bundesliga I | 2025/09/20 13:30 | Augsburg v Mainz | W | 1-4 |
| Germany Bundesliga I | 2025/09/13 13:30 | Mainz v RB Leipzig | L | 0-1 |
| Germany Bundesliga I | 2025/08/31 13:30 | Wolfsburg v Mainz | D | 1-1 |
| UEFA Conference League Qualifying | 2025/08/28 19:00 | Mainz v Rosenborg | W | 4-1 |
| Germany Bundesliga I | 2025/08/24 13:30 | Mainz v Cologne | L | 0-1 |
| UEFA Conference League Qualifying | 2025/08/21 16:00 | Rosenborg v Mainz | L | 2-1 |
| Germany DFB Pokal | 2025/08/18 16:00 | Dynamo Dresden v Mainz | W | 0-1 |
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